A metal-free protocol for direct oxidative de-alkoxycarbonylation of alkyl phenyl acetate by molecular iodine

A metal-free protocol for direct oxidative de-alkoxycarbonylation of alkyl phenyl acetate by molecular iodine

A metal-free protocol for the direct oxidative de-alkoxycarbonylation of alkyl phenyl acetate has been carried out by molecular iodine with good yield. In the present Letter, the vital role of iodine in oxidative de-alkoxycarbonylation is described. This method has been proven to be tolerant to a br...

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Veröffentlicht in:Tetrahedron letters 2014-04, Vol.55 (15), p.2337-2339
Hauptverfasser: Humne, Vivek T., Lokhande, Pradeep D.
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Carboxylic acid
Ethyl phenyl acetate
Functional groups
Iodine
Oxidative de-alkoxycarbonylation
Phenyls
Tetrahedrons
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Zusammenfassung:A metal-free protocol for the direct oxidative de-alkoxycarbonylation of alkyl phenyl acetate has been carried out by molecular iodine with good yield. In the present Letter, the vital role of iodine in oxidative de-alkoxycarbonylation is described. This method has been proven to be tolerant to a broad range of functional groups.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.02.049