1D Self-assembly of Terthiophene (3T)–Naphthalenediimide (NDI) Dyad

This work describes a strategy to create terthiophene (3T)–naphthalenediimide (NDI) nanostructures via the β-sheet self-assembly of a functionalized dipeptide. The dipeptide assembles into 1D nanofibers in organic solvents and forms a self-supporting organogel at low concentrations in CH2Cl2. The na...

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Veröffentlicht in:Chemistry letters 2014-10, Vol.43 (10), p.1634-1636
Hauptverfasser: Kim, Se Hye, Parquette, Jon R
Format: Artikel
Sprache:eng
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Zusammenfassung:This work describes a strategy to create terthiophene (3T)–naphthalenediimide (NDI) nanostructures via the β-sheet self-assembly of a functionalized dipeptide. The dipeptide assembles into 1D nanofibers in organic solvents and forms a self-supporting organogel at low concentrations in CH2Cl2. The nanostructures engage in extensive intermolecular π–π stacking interactions.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.140586