Synthesis of 4-benzyl-3-phenylbutenolide natural products

The first total synthesis of eutypoid A and a new synthesis of racemic microperfuranone and gymnoascolide A have been achieved. The key steps in our synthetic strategy involve a Suzuki coupling reaction to install the C3 aryl ring and a Mannich-type reaction for the construction of the 4-benzylbuten...

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Veröffentlicht in:	Tetrahedron letters 2013-09, Vol.54 (39), p.5322-5324
Hauptverfasser:	Parker, Anna N., Lock, Matthew J., Hutchison, John M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Chemical reactions Construction Eutypoid A Gymnoascolide A Mannich-type amino alkylation Microperfuranone Natural products Strategy Suzuki coupling Synthesis (chemistry) Tetrahedrons
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