Nitration of aromatic compounds under neutral conditions using the Ph sub(2PCl/I) sub(2)/AgNO sub(3 reagent system)

Nitration of aromatic compounds under neutral conditions using the Ph sub(2PCl/I) sub(2)/AgNO sub(3 reagent system)

Aromatic compounds were nitrated efficiently under essentially neutral conditions by employing Ph sub(2PCl in the presence of I) sub(2) and AgNO sub(3. This method minimizes waste products compared to traditional methods and gives the corresponding mononitro derivatives in good to excellent yields i...

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Veröffentlicht in:Tetrahedron letters 2011-09, Vol.52 (39), p.5081-5082
Hauptverfasser: Nowrouzi, Najmeh, Jonaghani, Mohammad Zareh
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Derivatives
Dichloromethane
Nitration
Tetrahedrons
Wastes
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Zusammenfassung:Aromatic compounds were nitrated efficiently under essentially neutral conditions by employing Ph sub(2PCl in the presence of I) sub(2) and AgNO sub(3. This method minimizes waste products compared to traditional methods and gives the corresponding mononitro derivatives in good to excellent yields in dichloromethane at room temperature.)
ISSN:0040-4039
DOI:10.1016/j.tetlet.2011.07.097