Synthesis of novel supramolecular triads bearing a H-bonded perylene bisimide core

Two novel hydrogen-bonded (H-bonded) triads consisting of triazine derivatives complexed with a perylene bisimide core were synthesized and characterized. NMR, UV/vis, and fluorescence spectra of these supramolecular triads confirmed the formation of strong multiple H-bonding, which were also proven...

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Veröffentlicht in:Tetrahedron 2012-09, Vol.68 (38), p.7926-7931
Hauptverfasser: Rajan, Yesudoss Christu, Shellaiah, Muthaiah, Huang, Ching-Ting, Lin, Hsin-Chieh, Lin, Hong-Cheu
Format: Artikel
Sprache:eng
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Zusammenfassung:Two novel hydrogen-bonded (H-bonded) triads consisting of triazine derivatives complexed with a perylene bisimide core were synthesized and characterized. NMR, UV/vis, and fluorescence spectra of these supramolecular triads confirmed the formation of strong multiple H-bonding, which were also proven to be nano-sized H-aggregates by X-ray diffraction (XRD) measurements. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2012.07.015