Fluorescent detection of anions by dibenzophenazine-based sensors

Binding studies of two sulfonamide-functionalized dibenzophenazine-based sensors are reported. Spectroscopic studies showed that both sensors are effective fluorescent turn-on sensors for several anions. Both sensors showed responses to acetate, benzoate, cyanide, and fluoride ions. NMR titrations c...

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Veröffentlicht in:Tetrahedron letters 2012-02, Vol.53 (6), p.661-665
Hauptverfasser: El-Ballouli, Ala’a O., Zhang, Yadong, Barlow, Stephen, Marder, Seth R., Al-Sayah, Mohammad H., Kaafarani, Bilal R.
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Sprache:eng
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Zusammenfassung:Binding studies of two sulfonamide-functionalized dibenzophenazine-based sensors are reported. Spectroscopic studies showed that both sensors are effective fluorescent turn-on sensors for several anions. Both sensors showed responses to acetate, benzoate, cyanide, and fluoride ions. NMR titrations confirmed the mode of binding of the sensors to be through H-bonding to the sulfonamide groups.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.11.121