Acyl migration from N to C in aziridine-2-carboxylic esters

Acyl group migration from N to C in aziridine-2-carboxylates takes place in deprotonation reactions and, as a result, aziridine-2,2-dicarboxylates are formed. Mechanistic studies proved that the observed migration is an intramolecular reaction. [Display omitted]

Bibliographische Detailangaben

Veröffentlicht in:	Tetrahedron 2014-01, Vol.70 (2), p.355-362
Hauptverfasser:	Strumfs, Boriss, Hermane, Jekaterina, Belyakov, Sergey, Trapencieris, Peteris
Format:	Artikel
Sprache:	eng
Schlagworte:	Acyl group migration Aziridine-2,2-dicarboxylates Aziridines Deprotonation Esters Lithium reagents Migration Tetrahedrons
Online-Zugang:	Volltext
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