Acyl migration from N to C in aziridine-2-carboxylic esters

Acyl migration from N to C in aziridine-2-carboxylic esters

Acyl group migration from N to C in aziridine-2-carboxylates takes place in deprotonation reactions and, as a result, aziridine-2,2-dicarboxylates are formed. Mechanistic studies proved that the observed migration is an intramolecular reaction. [Display omitted]

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Bibliographische Detailangaben
Veröffentlicht in:Tetrahedron 2014-01, Vol.70 (2), p.355-362
Hauptverfasser: Strumfs, Boriss, Hermane, Jekaterina, Belyakov, Sergey, Trapencieris, Peteris
Format: Artikel
Sprache:eng
Schlagworte:
Acyl group migration
Aziridine-2,2-dicarboxylates
Aziridines
Deprotonation
Esters
Lithium reagents
Migration
Tetrahedrons
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Zusammenfassung:Acyl group migration from N to C in aziridine-2-carboxylates takes place in deprotonation reactions and, as a result, aziridine-2,2-dicarboxylates are formed. Mechanistic studies proved that the observed migration is an intramolecular reaction. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2013.11.052