Simple and convenient synthesis of fluoroalkenes via direct coupling of alcohols, alkynes and fluoroboric acid under metal-free conditions
A novel and convenient method for the synthesis of fluoroalkenes from simple starting materials has been developed under mild and metal-free conditions. A novel and convenient method for the synthesis of fluoroalkenes from alkynes, alcohols and fluoroboric acid has been developed under mild conditio...
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| Veröffentlicht in: | Tetrahedron letters 2014-07, Vol.55 (28), p.3750-3752 |
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| creator | Yan, Xiao-wei Zhang, Qiang Wei, Wei Ji, Jian-xin |
| description | A novel and convenient method for the synthesis of fluoroalkenes from simple starting materials has been developed under mild and metal-free conditions.
A novel and convenient method for the synthesis of fluoroalkenes from alkynes, alcohols and fluoroboric acid has been developed under mild conditions. The present protocol provides an attractive approach to access various fluoroalkenes from simple and commercially available starting materials without any metal catalyst, ligand or additive. |
| doi_str_mv | 10.1016/j.tetlet.2014.05.069 |
| format | Article |
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A novel and convenient method for the synthesis of fluoroalkenes from alkynes, alcohols and fluoroboric acid has been developed under mild conditions. The present protocol provides an attractive approach to access various fluoroalkenes from simple and commercially available starting materials without any metal catalyst, ligand or additive.</description><subject>Additives</subject><subject>Alcohols</subject><subject>Alkynes</subject><subject>Coupling (molecular)</subject><subject>Fluoroalkenes</subject><subject>Fluoroboric acid</subject><subject>Ligands</subject><subject>Metal-free</subject><subject>Synthesis (chemistry)</subject><subject>Tetrahedrons</subject><issn>0040-4039</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKBDEQRYMoOD7-wEWWLuw2j35uBBFfMOBCXYdMUq0ZM8mYpAfmF_xq07Rra1NFce8t6iB0QUlJCW2u12WCZCGVjNCqJHVJmv4ALWjX8oLXHT1EC0IqUlSE98foJMY1ydV0ZIF-Xs1mawFLp7HybgfOgEs47l36hGgi9gMe7OiDl_YLHES8MxJrE0ClbBi31riPSSSt8p_exqs8fe0n4RQ5W1c-GIWlMhqPTkPAG0jSFkMAmI5qk4x38QwdDdJGOP_rp-j94f7t7qlYvjw-390uC1WROhUKOF_JljV1Lymr2Upr1mpGa6lXChTnwHVPJPA8t0PTVX1PuRymPWMw1PwUXc652-C_R4hJbExUYK104McoaFtVTcd7RrK0mqUq-BgDDGIbzEaGvaBETOjFWszoxYRekFpk9Nl2M9sgv7EzEERUGauCmZvQ3vwf8At0bpLu</recordid><startdate>20140709</startdate><enddate>20140709</enddate><creator>Yan, Xiao-wei</creator><creator>Zhang, Qiang</creator><creator>Wei, Wei</creator><creator>Ji, Jian-xin</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140709</creationdate><title>Simple and convenient synthesis of fluoroalkenes via direct coupling of alcohols, alkynes and fluoroboric acid under metal-free conditions</title><author>Yan, Xiao-wei ; Zhang, Qiang ; Wei, Wei ; Ji, Jian-xin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-ce33ba72659a1252bdd27d215adbcec33e3d90ae3ec37f6849913af33e322ef53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Additives</topic><topic>Alcohols</topic><topic>Alkynes</topic><topic>Coupling (molecular)</topic><topic>Fluoroalkenes</topic><topic>Fluoroboric acid</topic><topic>Ligands</topic><topic>Metal-free</topic><topic>Synthesis (chemistry)</topic><topic>Tetrahedrons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yan, Xiao-wei</creatorcontrib><creatorcontrib>Zhang, Qiang</creatorcontrib><creatorcontrib>Wei, Wei</creatorcontrib><creatorcontrib>Ji, Jian-xin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yan, Xiao-wei</au><au>Zhang, Qiang</au><au>Wei, Wei</au><au>Ji, Jian-xin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simple and convenient synthesis of fluoroalkenes via direct coupling of alcohols, alkynes and fluoroboric acid under metal-free conditions</atitle><jtitle>Tetrahedron letters</jtitle><date>2014-07-09</date><risdate>2014</risdate><volume>55</volume><issue>28</issue><spage>3750</spage><epage>3752</epage><pages>3750-3752</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><abstract>A novel and convenient method for the synthesis of fluoroalkenes from simple starting materials has been developed under mild and metal-free conditions.
A novel and convenient method for the synthesis of fluoroalkenes from alkynes, alcohols and fluoroboric acid has been developed under mild conditions. The present protocol provides an attractive approach to access various fluoroalkenes from simple and commercially available starting materials without any metal catalyst, ligand or additive.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2014.05.069</doi><tpages>3</tpages></addata></record> |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Additives Alcohols Alkynes Coupling (molecular) Fluoroalkenes Fluoroboric acid Ligands Metal-free Synthesis (chemistry) Tetrahedrons |
| title | Simple and convenient synthesis of fluoroalkenes via direct coupling of alcohols, alkynes and fluoroboric acid under metal-free conditions |
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