A new synthesis of alkyl (E)-(3-dimethylamino)acrylates

A highly stereoselective one-step method for the synthesis of alkyl (E)-(3-dimethylamino)acrylates from N,N-dimethylformamide and ketene acetals is reported.

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Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 2011-11, Vol.52 (46), p.6080-6081
Hauptverfasser:	Robertson, Jeffrey M., Jones, Ian W., Kayne, Kevin M., Contreras, Cristina G., Witter, Daniel J., Bates, Robert B., Hall, H.K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetals Acrylates Aliphatic compounds Chemistry Dimethylformamide Exact sciences and technology Ketene acetals Ketenes New synthetic method Organic chemistry Preparations and properties Synthesis (chemistry) Tetrahedrons Vilsmeier reagent
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Beschreibung
Zusammenfassung:	A highly stereoselective one-step method for the synthesis of alkyl (E)-(3-dimethylamino)acrylates from N,N-dimethylformamide and ketene acetals is reported.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.09.003