Inducing hysteretic spin crossover in solution

Inducing hysteretic spin crossover in solution

A hysteretic spin transition is induced in a solution assembly of a mononuclear Fe(III) amphiphilic complex which exhibits only gradual spin crossover in the solid state. The hysteretic behavior is dependent on dynamic solution assembly and removal of solvent causes reversion to the original bulk so...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-07, Vol.41 (25), p.7461-7463
Hauptverfasser: Martinho, Paulo N, Ortin, Yannick, Gildea, Brendan, Gandolfi, Claudio, McKerr, George, O'Hagan, Barry, Albrecht, Martin, Morgan, Grace G
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Crossovers
Dynamics
Hysteresis
Iron - chemistry
Methylene Chloride - chemistry
Microscopy, Electron, Scanning
Molecular Structure
Organometallic Compounds - chemistry
Reversion
Solid state
Solutions
Solvents
Spin transition
Surface-Active Agents - chemistry
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Beschreibung
Zusammenfassung:A hysteretic spin transition is induced in a solution assembly of a mononuclear Fe(III) amphiphilic complex which exhibits only gradual spin crossover in the solid state. The hysteretic behavior is dependent on dynamic solution assembly and removal of solvent causes reversion to the original bulk solid magnetic response.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12036d