Palladium-catalyzed direct thiolation of ethers with sodium sulfinates

Palladium-catalyzed direct thiolation of ethers with sodium sulfinates

[Display omitted] A new method for palladium-catalyzed arylthiolation of ethers with sodium sulfinates is described. The CH bond in various ethers was successfully converted into CS bond to yield the corresponding sulfides in moderate to good yields.

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Veröffentlicht in:Tetrahedron letters 2014-11, Vol.55 (47), p.6407-6410
Hauptverfasser: Guo, Shengrong, He, Weimin, Xiang, Jiannan, Yuan, Yanqin
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Ethers
Pd(OAc)2
Sodium
Sodium sulfinates
Sulfides
Tetrahedrons
Thiolation
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Zusammenfassung:[Display omitted] A new method for palladium-catalyzed arylthiolation of ethers with sodium sulfinates is described. The CH bond in various ethers was successfully converted into CS bond to yield the corresponding sulfides in moderate to good yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2014.09.098