Synthesis of polysiloxane xerogels with fluorine-containing groups in the surface layer and their sorption properties

The corpuscular fluorine-containing sorbents were synthesized. [Display omitted] ► Hydrophobic xerogels with surface fluorine-containing groups were synthesized ► We examined factors influencing structural-adsorption properties of xerogels ► Growing fluorinated chain increases affinity for n-hexane and decreases for water ► The obtained hybrid materials can be used for adsorption of hydrocarbons from water Hydrolysis and polycondensation reactions of tetraethoxysilane (TEOS) with 3,3,3-trifluoropropyl-trimethoxysilane (TFMS) or 1H,1H,2H,2H-perfluorooctyltriethoxysilane (PFES) were used to synthesize xerogels functionalized with fluorine-containing groups. According to transmission electron microscopy, the skeletons of synthesized polysiloxane xerogels have globular structures and consist of agglomerates of particles with fluorinated groups on their surfaces. FTIR spectroscopy showed that primary xerogel particles possess spatial polysiloxane networks, with fluorinated groups along with silanol groups and water in the surface layer. According to thermal analyses, the water content was 3–8 wt.%, and it decreased with increasing length of the fluorinated chain. Thermal destruction of the surface layer starts above 300 °C. The sorbents that were obtained were predominantly mesoporous materials with well-developed porous structures ( S BET = 400–960 m 2 g −1, V s = 0.66–0.93 cm 3 g −1). The influence of the TEOS/functional silane ratio and the natures of the functional groups on the structural and adsorptive properties were shown. The samples synthesized are organophilic. The affinity for n-hexane increases with increasing length of the fluorine-containing chain (PFES) and the content of fluorinated groups in the surface layer. The hybrid organic–inorganic materials that were obtained can be used for adsorption of hydrocarbons, including oil, from water.