A multi-component polyoxometalate and its catalytic performance for CO sub(2) cycloaddition reactions

A multi-component polyoxometalate and its catalytic performance for CO sub(2) cycloaddition reactions

A multi-component polyoxometalate based on earth-abundant elements (NH sub(4)) sub(10)[Co sub( 8)(H sub(2)O) sub(10)V sub(10)Mo sub(23)O sub(104) (OH) sub(6)].34.5H sub(2)O (1) has been successfully obtained and characterized. Furthermore, compound 1 acted as a Lewis acid catalyst and promoted the c...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-05, Vol.44 (22), p.10152-10155
Hauptverfasser: Chen, Shumin, Liu, Ying, Guo, Jipeng, Li, Pengzhen, Huo, Zhiyuan, Ma, Pengtao, Niu, Jingyang, Wang, Jingping
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Carbonates
Catalysis
Catalysts
Conversion
Cycloaddition
Lewis acid
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Zusammenfassung:A multi-component polyoxometalate based on earth-abundant elements (NH sub(4)) sub(10)[Co sub( 8)(H sub(2)O) sub(10)V sub(10)Mo sub(23)O sub(104) (OH) sub(6)].34.5H sub(2)O (1) has been successfully obtained and characterized. Furthermore, compound 1 acted as a Lewis acid catalyst and promoted the conversion of carbon dioxide to a cyclic carbonate under mild reaction conditions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01046b