Alkaloid induced asymmetric electrocarboxylation of 4-methylpropiophenone

The alkaloid-induced electrocarboxylation of 4-methylpropiophenone is examined in mild conditions. Comparative studies with several inductors indicate that the efficient enantiodiscrimination of the electrocarboxylation depends on the nucleophilic quinuclidine nitrogen atom and the OH group of the i...

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Veröffentlicht in:	Tetrahedron letters 2011-05, Vol.52 (21), p.2702-2705
Hauptverfasser:	Zhao, Shu-Feng, Zhu, Mei-Xia, Zhang, Kai, Wang, Huan, Lu, Jia-Xing
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaloids Asymmetry Carbon dioxide Chemistry Cinchonine Electrocarboxylation Electrochemistry Enantiomeric excess Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Induction Inductors Nitrogen atoms Organic chemistry Preparations and properties Tetrahedrons
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Beschreibung
Zusammenfassung:	The alkaloid-induced electrocarboxylation of 4-methylpropiophenone is examined in mild conditions. Comparative studies with several inductors indicate that the efficient enantiodiscrimination of the electrocarboxylation depends on the nucleophilic quinuclidine nitrogen atom and the OH group of the inductors.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.03.076