2-(Trimethylsilyl)ethanol as a new alcohol equivalent for copper-catalyzed coupling of aryl iodides

2-(Trimethylsilyl)ethanol as a new alcohol equivalent has been employed for copper-catalyzed coupling of aryl iodides. Using mild reaction conditions, it has been observed that substituted phenols and phenols with sensitive functional groups can be readily prepared.

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Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 2011-10, Vol.52 (41), p.5338-5341
Hauptverfasser:	Dibakar, Mullick, Prakash, Anjanappa, Selvakumar, Kumaravel, Ruckmani, Kandasamy, Sivakumar, Manickam
Format:	Artikel
Sprache:	eng
Schlagworte:	2-(Trimethylsilyl)ethanol Alcohol surrogates Alcohols Aromatic compounds Catalysis Catalytic reactions Chemistry Copper catalysis Cross-coupling Equivalence Exact sciences and technology Functional groups General and physical chemistry Iodides Joining Noncondensed benzenic compounds Organic chemistry Phenols Preparations and properties Tetrahedrons Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Beschreibung
Zusammenfassung:	2-(Trimethylsilyl)ethanol as a new alcohol equivalent has been employed for copper-catalyzed coupling of aryl iodides. Using mild reaction conditions, it has been observed that substituted phenols and phenols with sensitive functional groups can be readily prepared.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.08.023