Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

The reactions of [MCl(cod)]2 (M = Rh, Ir) with different NHC·HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)2] (M = Rh, Ir) is also reported.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (3), p.891-893
Hauptverfasser: Savka, R, Plenio, H
Format: Artikel
Sprache:eng
Schlagworte:
Acetone
Iridium
Synthesis (chemistry)
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Zusammenfassung:The reactions of [MCl(cod)]2 (M = Rh, Ir) with different NHC·HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)2] (M = Rh, Ir) is also reported.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt03449j