Tuning copper(II) ion selectivity: the role of basicity, size of the chelating ring and orientation of coordinating atoms

Incorporation of the triazolyl moiety modulates the basicity and effective size of the chelating ring, changes the stoichiometry in complex formation and thereby imparts Cu(2+) ion selectivity.

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Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-09, Vol.42 (36), p.12873-12877
Hauptverfasser:	Chereddy, Narendra Reddy, Korrapati, Purna Sai, Thennarasu, Sathiah, Mandal, Asit Baran
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals Basicity Chelating Chelating Agents - chemical synthesis Chelating Agents - chemistry Complex formation Copper - analysis Humans Magnetic Resonance Spectroscopy Mice NIH 3T3 Cells Orientation Rhodamines - chemical synthesis Rhodamines - chemistry Selectivity Spectrometry, Fluorescence Spectrometry, Mass, Electrospray Ionization Stoichiometry Triazoles - chemical synthesis Triazoles - chemistry Tuning
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Beschreibung
Zusammenfassung:	Incorporation of the triazolyl moiety modulates the basicity and effective size of the chelating ring, changes the stoichiometry in complex formation and thereby imparts Cu(2+) ion selectivity.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/c3dt51765a