Inorganic click (iClick) synthesis of heterotrinuclear Pt super(II)/Au super(I) sub(2) complexes

Inorganic click (iClick) synthesis of heterotrinuclear Pt super(II)/Au super(I) sub(2) complexes

Metal-azide-metal-acetylide cycloaddition (iClick) reactions to synthesize heterotrimetallics and an unexpected novel tetranuclear gold(i) complex, are described. In addition, a discussion regarding the connection between traditional azide-alkyne cycloaddition reactions and iClick is presented focus...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-10, Vol.42 (42), p.14963-14966
Hauptverfasser: Powers, Andrew R, Yang, Xi, Del Castillo, Trevor J, Ghiviriga, Ion, Abboud, Khalil A, Veige, Adam S
Format: Artikel
Sprache:eng
Schlagworte:
Cycloaddition
Joining
Linking
Metal ions
Synthesis (chemistry)
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Zusammenfassung:Metal-azide-metal-acetylide cycloaddition (iClick) reactions to synthesize heterotrimetallics and an unexpected novel tetranuclear gold(i) complex, are described. In addition, a discussion regarding the connection between traditional azide-alkyne cycloaddition reactions and iClick is presented focusing on applications towards linking multiple metal ions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt52105b