N-heterocyclic carbene-mediated transformations of silicon reagents

N-heterocyclic carbene-mediated transformations of silicon reagents

[Display omitted] This review summarizes developments in N-heterocyclic carbene-mediated transformation of silicon reagents over the past decade. Several reactions of silicon reagents, including the sila-Stetter reaction, 1,2-addition, carbon–carbon and carbon–oxygen double bond reduction, polymeriz...

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Veröffentlicht in:Tetrahedron letters 2015-02, Vol.56 (8), p.972-980
Hauptverfasser: He, Lin, Guo, Hao, Wang, Ying, Du, Guang-Fen, Dai, Bin
Format: Artikel
Sprache:eng
Schlagworte:
1,2-Addition
Bonding
Carbon-carbon composites
N-heterocyclic carbenes
Polymerization
Reduction
Silicon
Silicon reagents
Stetter reaction
Tetrahedrons
Transformations
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Zusammenfassung:[Display omitted] This review summarizes developments in N-heterocyclic carbene-mediated transformation of silicon reagents over the past decade. Several reactions of silicon reagents, including the sila-Stetter reaction, 1,2-addition, carbon–carbon and carbon–oxygen double bond reduction, polymerization, and other miscellaneous reactions, are discussed. The mechanisms of these reactions are also presented.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2015.01.034