Synthesis and atropisomerism of 2,2′-ortho disubstituted biphenyls

Synthesis and atropisomerism of 2,2′-ortho disubstituted biphenyls

The role of substitution on the aromatic rings for the synthesis of 2:2 disubstituted biphenyls has been investigated. Atropisomerism involved in the above ring system has been studied using NMR spectroscopy. The outcome of inter and intramolecular Heck reaction is discussed.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Tetrahedron letters 2010-12, Vol.51 (48), p.6213-6215
Hauptverfasser: Wang, C.H., Reilly, J., Brand, N., Schwartz, S., Alluri, S., Chan, T.M., Buevich, A.V., Ganguly, A.K.
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Atropisomerism
NMR spectroscopy
Radical cyclization
Synthesis (chemistry)
Tetrahedrons
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The role of substitution on the aromatic rings for the synthesis of 2:2 disubstituted biphenyls has been investigated. Atropisomerism involved in the above ring system has been studied using NMR spectroscopy. The outcome of inter and intramolecular Heck reaction is discussed.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2010.09.010