Synthesis and properties of 1,1′-bis(diacetylene-group) connected ferrocene–thiophene derivative: a cooperatively functional behavior of diacetylene-group connected constituents

An extended π-electronic conjugation system of 1,1′-bis(diacetylene-group) connected ferrocene–thiophene derivative has been synthesized, with our integrated reaction between the corresponding TMS-protected acetylenes in one-pot. Its electronic properties have been examined, suggesting a cooperative...

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Veröffentlicht in:	Tetrahedron letters 2011-08, Vol.52 (33), p.4295-4298
Hauptverfasser:	Yoshino, Junro, Hasegawa, Emi, Hayashi, Naoto, Higuchi, Hiroyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Conjugation Constituents Derivatives Diacetylene Electronic properties Electronic property Exact sciences and technology Ferrocene Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Integrated reaction Iron constituents Material science Organic chemistry Preparations and properties Synthesis (chemistry) Tetrahedrons Thiophene
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Zusammenfassung:	An extended π-electronic conjugation system of 1,1′-bis(diacetylene-group) connected ferrocene–thiophene derivative has been synthesized, with our integrated reaction between the corresponding TMS-protected acetylenes in one-pot. Its electronic properties have been examined, suggesting a cooperatively functional behavior of the diacetylene-group connected constituents.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.06.038