Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged Pt super(II)-Pt super(IV) Mixed-Valence Compound, {[Pt(en) sub(2)][PtCl sub(2)(en) sub(2)]} sub(3)(CuCl sub(4)) sub(4).12H sub(2)O

Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged Pt super(II)-Pt super(IV) Mixed-Valence Compound, {[Pt(en) sub(2)][PtCl sub(2)(en) sub(2)]} sub(3)(CuCl sub(4)) sub(4).12H sub(2)O

A new type of complex consisting of double liner-chain structure {[Pt(en) sub(2)][PtCl sub(2)(en) sub(2)]} sub(3)(CuCl sub(4)) sub(4).12H sub(2)O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (Pt super(III) component) formation was found. This unpr...

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Veröffentlicht in:Chemistry letters 2003-03, Vol.32 (3)
Hauptverfasser: Yamashita, Masahiro, Aso, Hidemitsu, Matsunaga, Satoshi, Takizawa, Koichi, Nakata, Kazuya, Kachi-Terajima, Chihiro, Iwahori, Fumiyasu, Ishii, Tomohiko, Miyasaka, Hitoshi, Sugiura, Ken-Ichi, Kawashima, Takuya, Takai, Kenzi, Kuroda, Noritaka, Shiro, Motoo, Kishida, Hideo, Okamoto, Hiroshi, Takahashi, Hiroyuki, Tanaka, Hisaaki, Marumoto, Kazuhiro, Kuroda, Shin-Ichi
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Sprache:eng
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Zusammenfassung:A new type of complex consisting of double liner-chain structure {[Pt(en) sub(2)][PtCl sub(2)(en) sub(2)]} sub(3)(CuCl sub(4)) sub(4).12H sub(2)O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (Pt super(III) component) formation was found. This unprecedented soliton formation mechanism will be discussed.
ISSN:0366-7022
DOI:10.1246/cl.2003.278