Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N‑Arylation

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N‑Arylation

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C–N and C–S bond formations and migratory N-arylation.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2015-11, Vol.137 (44), p.14071-14074
Hauptverfasser: Yoshida, Suguru, Yano, Takahisa, Misawa, Yoshihiro, Sugimura, Yasuyuki, Igawa, Kazunobu, Shimizu, Shigeomi, Tomooka, Katsuhiko, Hosoya, Takamitsu
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C–N and C–S bond formations and migratory N-arylation.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.5b10557