Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

Smallest optical gap for quasi-one-dimensional iodo-bridged platinum compounds

We synthesized a series of one-dimensional (1D) iodo-bridged platinum compounds with long alkyl chains on the counterions. In the compounds, the shortest Pt···Pt distance and the smallest band gap thus far reported were achieved. These compounds were found to be in a CDW state by using synchrotron X...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-01, Vol.42 (18), p.6277-6280
Hauptverfasser: Shin, Minseob, Takaishi, Shinya, Kumagai, Shohei, Ueda, Yutaro, Breedlove, Brian K, Matsuzaki, Hiroyuki, Okamoto, Hiroshi, Wakabayashi, Yusuke, Yamashita, Masahiro
Format: Artikel
Sprache:eng
Schlagworte:
Diffraction
Platinum compounds
Synchrotrons
X-rays
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We synthesized a series of one-dimensional (1D) iodo-bridged platinum compounds with long alkyl chains on the counterions. In the compounds, the shortest Pt···Pt distance and the smallest band gap thus far reported were achieved. These compounds were found to be in a CDW state by using synchrotron X-ray diffraction measurements.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt32890b