Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline

Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline

Treatment of [Cu(CH3CN)4]+ with 2-(4-dimethylaminophenyl)benzothiazoline in the presence of halide ions (X = Cl−, Br−, and I−) gave [Cu16L12X]3+ (L = (C6H4NMe2)CH=N(C6H4)S−) with a spherical Cu16S12 structure, while similar treatment in the absence of halide ions afforded [Cu8L8]2+ with a cyclic Cu8...

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Veröffentlicht in:Chemistry letters 2012, Vol.41 (3), p.334-336
Hauptverfasser: Takino, Yusuke, Yoshinari, Nobuto, Tsuge, Kiyoshi, Kawamoto, Tatsuya, Konno, Takumi
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Construction
Halides
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Zusammenfassung:Treatment of [Cu(CH3CN)4]+ with 2-(4-dimethylaminophenyl)benzothiazoline in the presence of halide ions (X = Cl−, Br−, and I−) gave [Cu16L12X]3+ (L = (C6H4NMe2)CH=N(C6H4)S−) with a spherical Cu16S12 structure, while similar treatment in the absence of halide ions afforded [Cu8L8]2+ with a cyclic Cu8S8 structure.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2012.334