Two new coordination polymers, a trinuclear metal complex and their interconversion depending on the solvent

Two new 1-D coordination polymers and a discrete trinuclear complex with a double-ring framework were synthesized and structurally characterized. The unique irreversible conversion from one of the 1-D coordination polymers to the trinuclear complex by contact with MeCN is described.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2014-09, Vol.43 (34), p.12832-12835
Hauptverfasser: Koike, Shiori, Hirakawa, Takeshi, Yamanishi, Katsunori, Kondo, Mitsuru
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Sprache:eng
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Zusammenfassung:Two new 1-D coordination polymers and a discrete trinuclear complex with a double-ring framework were synthesized and structurally characterized. The unique irreversible conversion from one of the 1-D coordination polymers to the trinuclear complex by contact with MeCN is described.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt01644k