Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn super(III)-substituted trilacunary Keggin tungstosilicate

Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn super(III)-substituted trilacunary Keggin tungstosilicate

A rare example of a "monomeric" triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-03, Vol.42 (14), p.5130-5139
Hauptverfasser: Shevchenko, Denys, Huang, Ping, Bon, Volodymyr V, Anderlund, Magnus F, Kokozay, Vladimir N, Styring, Stenbjorn, Thapper, Anders
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Crystal structure
Electrochemistry
Magnetism
Mass spectrometry
SQUIDs
Synthesis
X-rays
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Beschreibung
Zusammenfassung:A rare example of a "monomeric" triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt12500a