Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C-N, C-O and C-P bond

This Perspective article provides an overview of the recent advancements in the field of intra- and inter-molecular C-N, C-O and C-P bond formation by hydroamination, hydroalkoxylation, hydrophosphination, hydrophosphonylation or hydrophosphinylation of unactivated alkenes, including allenes, 1,3-di...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (27), p.1229-1259
Hauptverfasser: Rodriguez-Ruiz, Violeta, Carlino, Romain, Bezzenine-Lafollée, Sophie, Gil, Richard, Prim, Damien, Schulz, Emmanuelle, Hannedouche, Jérôme
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Sprache:eng
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Zusammenfassung:This Perspective article provides an overview of the recent advancements in the field of intra- and inter-molecular C-N, C-O and C-P bond formation by hydroamination, hydroalkoxylation, hydrophosphination, hydrophosphonylation or hydrophosphinylation of unactivated alkenes, including allenes, 1,3-dienes and strained alkenes, promoted by (chiral) homogeneous catalysts based on earth abundant elements of the s and p blocks, the first row transition metals and the rare-earth metals. The relevant literature from 2009 until late 2014 has been covered. This perspective provides an overview of the recent advancements in earth abundant element-based catalysts for alkene hydrofunctionalisation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt00280j