Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

Enhancing Ueff in oxime-bridged [MnIII6LnIII2] hexagonal prisms

The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH2) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(iii) ions with diamagnetic Ln(iii) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(iii) doubles Ueff.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (18), p.4797-4799
Hauptverfasser: Rigaux, Guillaume, Inglis, Ross, Morrison, Susan, Prescimone, Alessandro, Cadiou, Cyril, Evangelisti, Marco, Brechin, Euan K
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Diamagnetism
Magnetic properties
Prints
Prisms
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Zusammenfassung:The first 3d-4f clusters built using derivatised salicylaldoximes (R-saoH2) describe unusual hexagonal prisms. Replacement of the paramagnetic Gd(iii) ions with diamagnetic Ln(iii) ions allows for a more thorough understanding of the magnetic properties, whilst replacement with Tb(iii) doubles Ueff.
ISSN:1477-9226
1477-9234
DOI:10.1039/C1DT10154D