Tuning the coordination chemistry of a Cu(II) complex at high-pressure

Tuning the coordination chemistry of a Cu(II) complex at high-pressure

Application of pressure on the Cu-complex CuAsp causes Jahn-Teller Cu-O bonds to be compressed, increasing the coordination environment from [4 + 1] to [4 + 2], highlighted by a discontinuity on compression of these bonding interactions.

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Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-05, Vol.41 (18), p.5464-5467
Hauptverfasser: Gould, Jamie A, Rosseinsky, Matthew J, Moggach, Stephen A
Format: Artikel
Sprache:eng
Schlagworte:
Aspartic Acid - chemistry
BONDING
Compressed
Compressing
Coordination Complexes - chemistry
Copper
Copper - chemistry
Discontinuity
HIGH PRESSURE
Pressure
Tuning
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Beschreibung
Zusammenfassung:Application of pressure on the Cu-complex CuAsp causes Jahn-Teller Cu-O bonds to be compressed, increasing the coordination environment from [4 + 1] to [4 + 2], highlighted by a discontinuity on compression of these bonding interactions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12302a