Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Cationic complexes of silicon and germanium with (O,S)-chelate ligands

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH(2)CONMe(2))(2)(+)Cl(-) and MeGe(SCH(2)CONMe(2))(2)(+)Br(-) are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-11, Vol.41 (41), p.12681-12682
Hauptverfasser: Kalashnikova, Natalia A, Bylikin, Sergey Yu, Korlyukov, Aleksander A, Shipov, Aleksander G, Baukov, Yuri I, Taylor, Peter G, Bassindale, Alan R
Format: Artikel
Sprache:eng
Schlagworte:
Cationic
Coordination Complexes - chemistry
Diffraction
Distortion
Germanium
Germanium - chemistry
Ligands
Molecular Structure
Silicon
Silicon - chemistry
Synthesis
X-Ray Diffraction
X-rays
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Zusammenfassung:Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH(2)CONMe(2))(2)(+)Cl(-) and MeGe(SCH(2)CONMe(2))(2)(+)Br(-) are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31554h