How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen m...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-07, Vol.44 (26), p.11690-11695
Hauptverfasser: Tarrés, Màrius, Arderiu, Víctor S, Zaulet, Adnana, Viñas, Clara, Fabrizi de Biani, Fabrizia, Teixidor, Francesc
Format: Artikel
Sprache:eng
Schlagworte:
Benchmarking
Couples
Derivatives
Electric potential
Electrolysis - methods
Iron
Optimization
Organometallic Compounds - chemistry
Oxidation-Reduction
Paraquat - chemistry
Tuning
Voltage
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Beschreibung
Zusammenfassung:An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01464f