Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazola te bridging ligands

Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazola te bridging ligands

A redox-active dianionic N,O-phenolate-imidazolate/N,N-phenanthroline bridging ligand is used to form unique square-like neutral tetra-Cu(ii) assemblies, the structural, magnetic, electronic and redox properties of which are herein described.

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Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2013-01, Vol.42 (7), p.2358-2361
Hauptverfasser: Mathias, Jenny-Lee, Arora, Himanshu, Lavi, Ronit, Vezin, Herve, Yufit, Dmitry, Orio, Maylis, Aliaga-Alcade, Nuria, Benisvy, Laurent
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Bridging
Electronics
Ligands
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Beschreibung
Zusammenfassung:A redox-active dianionic N,O-phenolate-imidazolate/N,N-phenanthroline bridging ligand is used to form unique square-like neutral tetra-Cu(ii) assemblies, the structural, magnetic, electronic and redox properties of which are herein described.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32585c