Asymmetric transfer hydrogenation of imines in water/methanol co-solvent system and mechanistic investigation by DFT study

Asymmetric transfer hydrogenation of various cyclic imines proceeded efficiently with water/methanol co-solvent media in 20 min with excellent yields and enantioselectivities by employing Rh–TsDPEN catalyst and sodium formate as a hydrogen donor. The role of the co-solvent in enhanced productivity o...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	RSC advances 2014-01, Vol.4 (86), p.46351-46356
Hauptverfasser:	Shende, Vaishali S., Shingote, Savita K., Deshpande, Sudhindra H., Kuriakose, Nishamol, Vanka, Kumar, Kelkar, Ashutosh A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Catalysts Hydrogen storage Hydrogenation Imines Methyl alcohol Productivity Sodium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!