A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

Polyoxoniobate clusters that are stable in acidic solutions are rare and particularly useful in industrial processes. Here we report a new pentaphosphate niobate polyoxometalate cluster (TMA)9H3Nb9P5O41·28H2O (Nb9P5) that is stable over a wide pH range and that can be converted reversibly into the p...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (64), p.12744-12747
Hauptverfasser: Son, Jung-Ho, Casey, William H
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Hydrogen peroxide
Hydrogen Peroxide - chemistry
Hydrogen-Ion Concentration
Models, Molecular
Molecular Conformation
Niobates
Niobium - chemistry
Phosphates - chemistry
Tungsten Compounds - chemistry
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Zusammenfassung:Polyoxoniobate clusters that are stable in acidic solutions are rare and particularly useful in industrial processes. Here we report a new pentaphosphate niobate polyoxometalate cluster (TMA)9H3Nb9P5O41·28H2O (Nb9P5) that is stable over a wide pH range and that can be converted reversibly into the peroxo form.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc03782d