A hydrogen bonded molecular capsule versus a 3D network of tripodal organopolysilanols
1,3,5-Triethylbenzene based tripodal trisilanols were synthesized. The X-ray crystal structures of trisilanols showed capsule formation as well as non-capsular network formation using silanol hydrogen bonds. The (1)H NMR and ESI-mass spectroscopy experiments for solution state binding supported enca...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (79), p.14746-14749 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | 1,3,5-Triethylbenzene based tripodal trisilanols were synthesized. The X-ray crystal structures of trisilanols showed capsule formation as well as non-capsular network formation using silanol hydrogen bonds. The (1)H NMR and ESI-mass spectroscopy experiments for solution state binding supported encapsulation of the halide ions in the cavity of the molecular capsule with a C3 symmetry. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c5cc04515k |