Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]

Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]

We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]−. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]− using state‐of‐the‐art quantum chemical methods. The synthesis and spectroscopic characterization of the boron d...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2015-09, Vol.54 (38), p.11078-11083
Hauptverfasser: Zhang, Qingnan, Li, Wan-Lu, Xu, Cong-Qiao, Chen, Mohua, Zhou, Mingfei, Li, Jun, Andrada, Diego M., Frenking, Gernot
Format: Artikel
Sprache:eng
Schlagworte:
bonding analysis
boron dicarbonyl compound
matrix isolation
quantum chemical calculations
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]−. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]− using state‐of‐the‐art quantum chemical methods. The synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]− is reported. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]− using state‐of‐the‐art quantum chemical methods.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201503686