On the utilization of a lignocellulosic waste as an excellent dye remover: Modification, characterization and mechanism analysis

•CTAB modified SMSBP has excellent biosorption performance for RR2 removal.•The removal process followed Langmuir isotherm and pseudo-second-order kinetics.•RR2 biosorption by SMSBP endothermically occurred.•Biosorption mechanism, desorption and usability in real conditions were explored. Biosorptio...

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Veröffentlicht in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2013-08, Vol.229, p.257-266
Hauptverfasser: Akar, Sibel Tunali, Yilmazer, Dilek, Celik, Sema, Balk, Yasemin Yetimoglu, Akar, Tamer
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Sprache:eng
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Zusammenfassung:•CTAB modified SMSBP has excellent biosorption performance for RR2 removal.•The removal process followed Langmuir isotherm and pseudo-second-order kinetics.•RR2 biosorption by SMSBP endothermically occurred.•Biosorption mechanism, desorption and usability in real conditions were explored. Biosorption potential of sugar beet pulp was significantly improved via grafting by quaternary ammonium salt. Initial pH, biosorbent dosage, contact time, temperature and flow rate were investigated as design parameters. A higher biosorption yield, shorter period of equilibrium time and lower amount of biosorbent were recorded as the main characteristics for batch mode decolorization. The pseudo-second-order model better fitted the kinetic data while Langmuir isotherm model is found to be best represent the biosorption equilibrium. Thermodynamic findings indicated that the nature of Reactive Red 2 (RR2) biosorption is endothermic and spontaneous. The modified sugar beet pulp was also successfully used in dynamic flow mode removal of RR2. Recovery of biosorbed RR2 from the modified biomaterial was investigated in alkaline solutions and good values were observed. IR, SEM, AFM, EDX, potentiometric titration and zeta potential studies were used to characterize the biosorbent structure in addition to real sample application of modified biomaterial.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2013.06.009