Heterogeneous mineral assemblages in martian meteorite Tissint as a result of a recent small impact event on Mars

•The mineralogy within and adjacent to shock melts in shergottite Tissint are characterized.•The distribution of high pressure phases is heterogeneous and is a function of the post-shock thermal history of the sample.•Shock effects in Tissint are consistent with their formation in a recent small imp...

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Veröffentlicht in:Geochim. Cosmochim. Acta 2014-09, Vol.140 (9, 2014), p.334-348
Hauptverfasser: Walton, E.L., Sharp, T.G., Hu, J., Filiberto, J.
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Sprache:eng
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Zusammenfassung:•The mineralogy within and adjacent to shock melts in shergottite Tissint are characterized.•The distribution of high pressure phases is heterogeneous and is a function of the post-shock thermal history of the sample.•Shock effects in Tissint are consistent with their formation in a recent small impact event on Mars. The microtexture and mineralogy of shock melts in the Tissint martian meteorite were investigated using scanning electron microscopy, Raman spectroscopy, transmission electron microscopy and synchrotron micro X-ray diffraction to understand shock conditions and duration. Distinct mineral assemblages occur within and adjacent to the shock melts as a function of the thickness and hence cooling history. The matrix of thin veins and pockets of shock melt consists of clinopyroxene+ringwoodite±stishovite embedded in glass with minor Fe-sulfide. The margins of host rock olivine in contact with the melt, as well as entrained olivine fragments, are now amorphosed silicate perovskite+magnesiowüstite or clinopyroxene+magnesiowüstite. The pressure stabilities of these mineral assemblages are ∼15GPa and >19GPa, respectively. The ∼200-μm-wide margin of a thicker, mm-size (up to 1.4mm) shock melt vein contains clinopyroxene+olivine, with central regions comprising glass+vesicles+Fe-sulfide spheres. Fragments of host rock within the melt are polycrystalline olivine (after olivine) and tissintite+glass (after plagioclase). From these mineral assemblages the crystallization pressure at the vein edge was as high as 14GPa. The interior crystallized at ambient pressure. The shock melts in Tissint quench-crystallized during and after release from the peak shock pressure; crystallization pressures and those determined from olivine dissociation therefore represent the minimum shock loading. Shock deformation in host rock minerals and complete transformation of plagioclase to maskelynite suggest the peak shock pressure experienced by Tissint⩾29–30GPa. These pressure estimates support our assessment that the peak shock pressure in Tissint was significantly higher than the minimum 19GPa required to transform olivine to silicate perovskite plus magnesiowüstite. Small volumes of shock melt (
ISSN:0016-7037
1872-9533
DOI:10.1016/j.gca.2014.05.023