Electron Reconfiguration and Enhanced Phonon Activation in the Superconducting State of a FeSe sub( 0.3)Te sub( 0.7) Single Crystal, as Evidenced by Mossbauer Spectroscopy

The Mossbauer spectra of a ... single crystal grown by the Bridgman method were analysed across the superconducting transition by considering the interplay between the structure and electron configuration of the transition metal. The magnetically determined superconducting critical temperature is TC ~ 14 K. The 57Fe Mossbauer spectra collected in the temperature range from 5 to 200 K mainly have an asymmetric doublet pattern, which was conveniently fitted by the full Hamiltonian method. No effective magnetic moment ascribed to the superconducting phase was observed down to 5 K. The unusual behaviour observed below ~17 K for the chemical isomer shift and quadrupole splitting may be associated with an electron reconfiguration process intimately related to an unusual lattice distortion accompanying the superconducting transition. The decreasing trend of the total absorption spectral area and second-order Doppler shift during cooling the sample below the critical temperature, point to enhanced phonon activation in the superconducting state. (ProQuest: ... denotes formulae/symbols omitted.)