Metal-Free Oxidative Decarbonylative Coupling of Aliphatic Aldehydes with Azaarenes: Successful Minisci-Type Alkylation of Various Heterocycles

A metal‐free oxidative decarbonylative coupling of aliphatic aldehydes with various electron‐deficient heterocycles has been developed. This reaction is supposed to be realized via a Minisci‐type mechanism, based on the substrate scope, regioselectivity and radical trapping experiments. The ready av...

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Veröffentlicht in:	Advanced synthesis & catalysis 2015-06, Vol.357 (9), p.2055-2060
Hauptverfasser:	Tang, Ren-Jin, Kang, Lei, Yang, Luo
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Aliphatic compounds Alkylation Availability Biocompatibility decarbonylation heterocycles Joining metal-free conditions Radicals Synthesis
Online-Zugang:	Volltext
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