Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6](27-) based on abundant metals

Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6](27-) based on abundant metals

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOF(initial)) of 6.3 s(-1) over were achieve...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-09, Vol.51 (73), p.13925-13928
Hauptverfasser: Du, Xiaoqiang, Ding, Yong, Song, Fangyuan, Ma, Baochun, Zhao, Junwei, Song, Jie
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Light
Metals - chemistry
Oxidation-Reduction
Photochemical Processes
Tungsten Compounds - chemistry
Water - chemistry
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Zusammenfassung:An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOF(initial)) of 6.3 s(-1) over were achieved for water oxidation.
ISSN:1364-548X
DOI:10.1039/c5cc04551g