Major element geochemistry and paleoclimatology of the Permo-Carboniferous glacigene Dwyka Formation and post-glacial mudrocks in southern Africa

A Chemical Index of Alteration (CIA) is used to quantify the degree of weathering of fine-grained materials in the glacigenic Permo-Carboniferous Dwyka Formation and succeeding stratigraphic units of southern Africa. Diamictites in the Dwyka Formation have low CIA values compatible with their glacigenic origin. Interbedded mudrocks show a wide scatter of values, suggesting that at least some of them were deposited during periods when ice had retreated from the source areas. Samples from the Prince Albert shale, which immediately overlies the Dwyka formation, show high CIA values, suggesting a rapid transition to a much more intensive weathering regime (warmer climatic conditions?). Samples from the succeeding Whitehill shale have a low average value, so that weathering was once more inhibited, perhaps by a temporary return to a colder climate. The highest stratigraphic units sampled, the "upper shales", have an average CIA value comparable to that of "average" shales, and suggesting "normal" weathering conditions. Major element geochemical data can supplement sedimentological and paleontological information and provide a valuable contribution to the detailed paleoclimatic interpretation of such glacigenic successions.