Metal Iodate-Based Energetic Composites and Their Combustion and Biocidal Performance

The biological agents that can be weaponized, such as Bacillus anthracis, pose a considerable potential public threat. Bacterial spores, in particular, are highly stress resistant and cannot be completely neutralized by common bactericides. This paper reports on synthesis of metal iodate-based aluminized electrospray-assembled nanocomposites which neutralize spores through a combined thermal and chemical mechanism. Here metal iodates (Bi­(IO3)3, Cu­(IO3)2, and Fe­(IO3)3) act as a strong oxidizer to nanoaluminum to yield a very exothermic and violent reaction, and simultaneously generate iodine as a long-lived bactericide. These microparticle-assembled nanocomposites when characterized in terms of reaction times and temporal pressure release show significantly improved reactivity. Furthermore, sporicidal performance superior to conventional metal-oxide-based thermites clearly shows the advantages of combining both a thermal and biocidal mechanism in spore neutralization.