Highly Efficient Dehydrogenation of Formic Acid over a Palladium-Nanoparticle-Based Mott-Schottky Photocatalyst

Exploiting useful contacts: The exceptional catalytic performance of a photocatalyst composed of Pd nanoparticles and mesoporous carbon nitride for the dehydrogenation of formic acid in water at room temperature to produce H2 gas (see picture) is due to enhanced electron enrichment of the Pd nanopar...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-11, Vol.52 (45), p.11822-11825
Hauptverfasser: Cai, Yi-Yu, Li, Xin-Hao, Zhang, Ya-Nan, Wei, Xiao, Wang, Kai-Xue, Chen, Jie-Sheng
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container_end_page 11825
container_issue 45
container_start_page 11822
container_title Angewandte Chemie International Edition
container_volume 52
creator Cai, Yi-Yu
Li, Xin-Hao
Zhang, Ya-Nan
Wei, Xiao
Wang, Kai-Xue
Chen, Jie-Sheng
description Exploiting useful contacts: The exceptional catalytic performance of a photocatalyst composed of Pd nanoparticles and mesoporous carbon nitride for the dehydrogenation of formic acid in water at room temperature to produce H2 gas (see picture) is due to enhanced electron enrichment of the Pd nanoparticles through charge transfer at the interface of the Mott–Schottky contact.
doi_str_mv 10.1002/anie.201304652
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source Wiley Online Library Journals Frontfile Complete
subjects Carbon nitride
Catalysis
Charge transfer
Dehydrogenation
Formic acid
heterogeneous catalysis
hydrogen generation
Mott-Schottky catalysts
Nanoparticles
nanostructures
Palladium
Photocatalysis
title Highly Efficient Dehydrogenation of Formic Acid over a Palladium-Nanoparticle-Based Mott-Schottky Photocatalyst
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