Highly Efficient Dehydrogenation of Formic Acid over a Palladium-Nanoparticle-Based Mott-Schottky Photocatalyst

Exploiting useful contacts: The exceptional catalytic performance of a photocatalyst composed of Pd nanoparticles and mesoporous carbon nitride for the dehydrogenation of formic acid in water at room temperature to produce H2 gas (see picture) is due to enhanced electron enrichment of the Pd nanopar...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-11, Vol.52 (45), p.11822-11825
Hauptverfasser: Cai, Yi-Yu, Li, Xin-Hao, Zhang, Ya-Nan, Wei, Xiao, Wang, Kai-Xue, Chen, Jie-Sheng
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Sprache:eng
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Zusammenfassung:Exploiting useful contacts: The exceptional catalytic performance of a photocatalyst composed of Pd nanoparticles and mesoporous carbon nitride for the dehydrogenation of formic acid in water at room temperature to produce H2 gas (see picture) is due to enhanced electron enrichment of the Pd nanoparticles through charge transfer at the interface of the Mott–Schottky contact.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201304652