Kinetics of the Fischer-Tropsch Reaction

Kinetics of the Fischer-Tropsch Reaction

Long carbon chains: Self‐assembly of monomeric carbon intermediates into long‐chain hydrocarbons on catalytically reactive surface (see picture) was studied when full reversibility of the chain growth is included in the kinetic model. Using Brønsted–Evans–Polanyi relations, the maximum chain growth...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-09, Vol.51 (36), p.9015-9019
Hauptverfasser: Markvoort, Albert J., van Santen, Rutger A., Hilbers, Peter A. J., Hensen, Emiel J. M.
Format: Artikel
Sprache:eng
Schlagworte:
Carbon
Carbon Monoxide - chemistry
Catalysis
Fischer-Tropsch reaction
heterogeneous catalysis
Hydrocarbons
Hydrocarbons - chemistry
Hydrogen - chemistry
Kinetics
Mathematical models
Pictures
Reaction kinetics
Self assembly
Surface Properties
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Beschreibung
Zusammenfassung:Long carbon chains: Self‐assembly of monomeric carbon intermediates into long‐chain hydrocarbons on catalytically reactive surface (see picture) was studied when full reversibility of the chain growth is included in the kinetic model. Using Brønsted–Evans–Polanyi relations, the maximum chain growth as a function of the surface reactivity is predicted.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201203282