Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter
Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetri...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2013-12, Vol.52 (52), p.14021-14025 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 14025 |
|---|---|
| container_issue | 52 |
| container_start_page | 14021 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 52 |
| creator | Chen, Liang-An Tang, Xiaojuan Xi, Jianwei Xu, Weici Gong, Lei Meggers, Eric |
| description | Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetric induction. |
| doi_str_mv | 10.1002/anie.201306997 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1701123487</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1701123487</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5477-af8b2cd476ed4deb438b8cac48f4932a20919dc7f4fe02d741d72a56555e12183</originalsourceid><addsrcrecordid>eNqFkc1v1DAQxS1ERcvClSOyxIVLtv5K7ByXqJRVl61QC0hcLMeZaF3y0dqOYP97HG1ZIS49zWjm957leQi9oWRJCWHnZnCwZIRyUpSlfIbOaM5oxqXkz1MvOM-kyukpehnCXeKVIsULdMoEm3f8DMVq57zpMhOzzxBNh69tNDto0gyvvWvc1OPKpMU-RNyOHscd4FXY9z1E7yyuxiFEP9noxgGPLTYDXnVdVhlfp8GXyUTwg_F7fJMaGC0Mqb5CJ63pArx-rAv09ePFbfUp21xfrqvVJrO5kDIzraqZbYQsoBEN1IKrWlljhWpFyZlhpKRlY2UrWiCskYI2kpm8yPMcKKOKL9D7g--9Hx8mCFH3LljoOjPAOAVNJaGUcaHk06goyXzJhC_Qu__Qu3FKn-xmqlClYHk5v708UNaPIXho9b13fbqEpkTP0ek5On2MLgnePtpOdQ_NEf-bVQLKA_DLdbB_wk6vtuuLf82zg9aFCL-PWuN_6kJymevv20t9tf0mP1xtfuiK_wGbeLSi</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1468942598</pqid></control><display><type>article</type><title>Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Chen, Liang-An ; Tang, Xiaojuan ; Xi, Jianwei ; Xu, Weici ; Gong, Lei ; Meggers, Eric</creator><creatorcontrib>Chen, Liang-An ; Tang, Xiaojuan ; Xi, Jianwei ; Xu, Weici ; Gong, Lei ; Meggers, Eric</creatorcontrib><description>Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetric induction.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201306997</identifier><identifier>PMID: 24214333</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>asymmetric catalysis ; Asymmetry ; Carbon - chemistry ; Catalysis ; Chirality ; Construction ; Formations ; hydrogen bonds ; Inert ; Iridium ; Iridium - chemistry ; Ligands ; Peptides - chemistry ; quaternary stereocenter ; Sole ; Stereoisomerism</subject><ispartof>Angewandte Chemie International Edition, 2013-12, Vol.52 (52), p.14021-14025</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5477-af8b2cd476ed4deb438b8cac48f4932a20919dc7f4fe02d741d72a56555e12183</citedby><cites>FETCH-LOGICAL-c5477-af8b2cd476ed4deb438b8cac48f4932a20919dc7f4fe02d741d72a56555e12183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201306997$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201306997$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24214333$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Liang-An</creatorcontrib><creatorcontrib>Tang, Xiaojuan</creatorcontrib><creatorcontrib>Xi, Jianwei</creatorcontrib><creatorcontrib>Xu, Weici</creatorcontrib><creatorcontrib>Gong, Lei</creatorcontrib><creatorcontrib>Meggers, Eric</creatorcontrib><title>Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetric induction.</description><subject>asymmetric catalysis</subject><subject>Asymmetry</subject><subject>Carbon - chemistry</subject><subject>Catalysis</subject><subject>Chirality</subject><subject>Construction</subject><subject>Formations</subject><subject>hydrogen bonds</subject><subject>Inert</subject><subject>Iridium</subject><subject>Iridium - chemistry</subject><subject>Ligands</subject><subject>Peptides - chemistry</subject><subject>quaternary stereocenter</subject><subject>Sole</subject><subject>Stereoisomerism</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc1v1DAQxS1ERcvClSOyxIVLtv5K7ByXqJRVl61QC0hcLMeZaF3y0dqOYP97HG1ZIS49zWjm957leQi9oWRJCWHnZnCwZIRyUpSlfIbOaM5oxqXkz1MvOM-kyukpehnCXeKVIsULdMoEm3f8DMVq57zpMhOzzxBNh69tNDto0gyvvWvc1OPKpMU-RNyOHscd4FXY9z1E7yyuxiFEP9noxgGPLTYDXnVdVhlfp8GXyUTwg_F7fJMaGC0Mqb5CJ63pArx-rAv09ePFbfUp21xfrqvVJrO5kDIzraqZbYQsoBEN1IKrWlljhWpFyZlhpKRlY2UrWiCskYI2kpm8yPMcKKOKL9D7g--9Hx8mCFH3LljoOjPAOAVNJaGUcaHk06goyXzJhC_Qu__Qu3FKn-xmqlClYHk5v708UNaPIXho9b13fbqEpkTP0ek5On2MLgnePtpOdQ_NEf-bVQLKA_DLdbB_wk6vtuuLf82zg9aFCL-PWuN_6kJymevv20t9tf0mP1xtfuiK_wGbeLSi</recordid><startdate>20131223</startdate><enddate>20131223</enddate><creator>Chen, Liang-An</creator><creator>Tang, Xiaojuan</creator><creator>Xi, Jianwei</creator><creator>Xu, Weici</creator><creator>Gong, Lei</creator><creator>Meggers, Eric</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20131223</creationdate><title>Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter</title><author>Chen, Liang-An ; Tang, Xiaojuan ; Xi, Jianwei ; Xu, Weici ; Gong, Lei ; Meggers, Eric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5477-af8b2cd476ed4deb438b8cac48f4932a20919dc7f4fe02d741d72a56555e12183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>asymmetric catalysis</topic><topic>Asymmetry</topic><topic>Carbon - chemistry</topic><topic>Catalysis</topic><topic>Chirality</topic><topic>Construction</topic><topic>Formations</topic><topic>hydrogen bonds</topic><topic>Inert</topic><topic>Iridium</topic><topic>Iridium - chemistry</topic><topic>Ligands</topic><topic>Peptides - chemistry</topic><topic>quaternary stereocenter</topic><topic>Sole</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Liang-An</creatorcontrib><creatorcontrib>Tang, Xiaojuan</creatorcontrib><creatorcontrib>Xi, Jianwei</creatorcontrib><creatorcontrib>Xu, Weici</creatorcontrib><creatorcontrib>Gong, Lei</creatorcontrib><creatorcontrib>Meggers, Eric</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Liang-An</au><au>Tang, Xiaojuan</au><au>Xi, Jianwei</au><au>Xu, Weici</au><au>Gong, Lei</au><au>Meggers, Eric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2013-12-23</date><risdate>2013</risdate><volume>52</volume><issue>52</issue><spage>14021</spage><epage>14025</epage><pages>14021-14025</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert bis‐cyclometalated iridium complex (see picture). In this complex, the metal‐centered chirality serves as the sole source for the effective asymmetric induction.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>24214333</pmid><doi>10.1002/anie.201306997</doi><tpages>5</tpages><edition>International ed. in English</edition></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2013-12, Vol.52 (52), p.14021-14025 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1701123487 |
| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | asymmetric catalysis Asymmetry Carbon - chemistry Catalysis Chirality Construction Formations hydrogen bonds Inert Iridium Iridium - chemistry Ligands Peptides - chemistry quaternary stereocenter Sole Stereoisomerism |
| title | Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-15T14%3A49%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chiral-at-Metal%20Octahedral%20Iridium%20Catalyst%20for%20the%20Asymmetric%20Construction%20of%20an%20All-Carbon%20Quaternary%20Stereocenter&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Chen,%20Liang-An&rft.date=2013-12-23&rft.volume=52&rft.issue=52&rft.spage=14021&rft.epage=14025&rft.pages=14021-14025&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201306997&rft_dat=%3Cproquest_cross%3E1701123487%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1468942598&rft_id=info:pmid/24214333&rfr_iscdi=true |