3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials

3D Energetic Metal-Organic Frameworks: Synthesis and Properties of High Energy Materials

Energetic 3D MOFs: A structurally unique class of three‐dimensional energetic metal–organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF sh...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-12, Vol.52 (52), p.14031-14035
Hauptverfasser: Li, Shenghua, Wang, Yuan, Qi, Cai, Zhao, Xiuxiu, Zhang, Jichuan, Zhang, Shaowen, Pang, Siping
Format: Artikel
Sprache:eng
Schlagworte:
Detonation
Electrostatic discharges
energetic materials
Friction
heats of detonation
mesoporous materials
Metal-organic frameworks
nitrogen-rich heterocycles
Synthesis
Thermal stability
Three dimensional
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Zusammenfassung:Energetic 3D MOFs: A structurally unique class of three‐dimensional energetic metal–organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g−1.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201307118